专利摘要:
Polymer membrane, obtaining procedure, uses thereof and detection method of furfural and/or 5-hydroxymethylfurfural. The present invention relates to a polymeric membrane of acrylate and/or methacrylate type comprising aniline, unsubstituted in the amino group, or a derivative thereof, to the process for obtaining the membrane, and to the uses given thereto. . The present invention relates to the detection of compounds that mark the freshness of foods, such as furfural and 5-hydroxymethylfurfural (5-hmf). More specifically, the present invention describes a method for detecting furfural and/or 5-hmf in a sample by detecting a color change, in a polymer membrane comprising aniline. (Machine-translation by Google Translate, not legally binding)
公开号:ES2539863A1
申请号:ES201430002
申请日:2014-01-02
公开日:2015-07-06
发明作者:María Cruz Moreno Bondi;María Elena BENITO PEÑA;María Victoria GONZÁLEZ DE VALLEJO RODRÍGUEZ;Alberto RICO YUSTE;Janire PEÑA BAHAMONDE;Benet FITÉ LUIS;Jaume LLUÍS TARTERA
申请人:Universidad Complutense de Madrid;Mahou SA;
IPC主号:
专利说明:

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P201430002
01-02-2014
present in a food simulant, water: ethanol (94.6: 5.4;% v / v). The maximum wavelength at 537 nm is taken. DETAILED EXHIBITION OF THE INVENTION
As mentioned above, one aspect of the present invention relates to a polymeric membrane comprising aniline monomers and acrylate or methacrylate monomers with ethylenically unsaturated groups.
10 The term "ethylenically unsaturated group" is used here in a broad sense and is intended to encompass any of the groups containing a group -C = C-.
Examples of methacrylate or acrylate monomers are: 2-hydroxyethyl 2-methylprop-2-enoate (HEMA) or 2- (2-methyl-acryloyloxy) ethyl 2-methyl acrylate (EDMA). Particularly the aniline derivative is 4-vinylaniline.
Preferably, the thickness of the membrane is between 0.5 mm and 1.2 mm.
20 Preferably the sample is a food sample.
In the process for obtaining the membrane of the invention a polymerization initiating compound is used. In the present invention the "polymerization initiating compound" refers to a chemical compound that initiates the polymerization reaction
25 by radio route through the use of thermal energy or with UV light. Examples of suitable radical initiators include, but are not limited to, 2,2'-azobis (2,4-dimethylpentanenitrile), 2,2'-azobis (2-methylpropanonitrile), 2,2'-azobis (2-methylbutanenitrile), peroxides such as benzoyl peroxide, and the like. Preferably the polymerization initiator is 2.2 azobis- (2,4-dimethylvaleronitrile) (ABDV).
In addition, in the process for obtaining the membrane of the invention, once the solutions of the different monomers have been prepared, the mixture is deposited on a support. Preferably the support is two glass plates and the polymer is deposited between them.
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权利要求:
Claims (1)
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引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题
GB1051374A|
US2728751A|1953-02-25|1955-12-27|Du Pont|Long chain acrylic type ester/aminostyrene copolymers|
WO1998032012A1|1997-01-15|1998-07-23|University Of Strathclyde|Furfuraldehyde detector and method of manufacturing the same|
US20070287183A1|2004-10-15|2007-12-13|Berthold Wagner|Agent and Method for Identifying Furfurals|
CN106546667A|2015-09-18|2017-03-29|华仁药业股份有限公司|The detection method of 5 hydroxymethyl furfural in a kind of peritoneal dialysis solution|
法律状态:
2015-02-03| PC2A| Transfer of patent|Owner name: MAHOU, S.A. Effective date: 20150128 |
2016-04-13| FG2A| Definitive protection|Ref document number: 2539863 Country of ref document: ES Kind code of ref document: B1 Effective date: 20160413 |
优先权:
申请号 | 申请日 | 专利标题
ES201430002A|ES2539863B1|2014-01-02|2014-01-02|Polymeric membrane, method of obtaining, uses thereof and method of detection of furfural and / or 5-hydroxymethylfurfural|ES201430002A| ES2539863B1|2014-01-02|2014-01-02|Polymeric membrane, method of obtaining, uses thereof and method of detection of furfural and / or 5-hydroxymethylfurfural|
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